Why does light absorb? The quantum mechanical model is a bit opaque and doesn't tell us much. Let's use the classical model instead.
Molecules are composed of charged particles. Light (an E&M field) exerts a force on these charges. Force exerted on the molecules depends on the field strength, magnitude of the charges, and how far the charges move.
- Light: an oscillating electric magnetic field
- Matter: we treat it as a harmonic oscilattor
- Interactions: oscillating external force field driving a harmonic oscillator
- Let's propogate along and drop polarization so
We can also drop the wave vector
Why should we be able to call molecules harmonic oscillators? i.e., a mass on a spring?
Molecules feel a restoring force when pushed from equilibrium.
The covalent bond can be thought of as a spring. The equilibrium length is a balance between attractive and repulsive forces. \ If we push/pull on this bond, there is a restoring force that pushes the system back to equilibrium.
This analogy works for other systems also
- Electronic states—think of pushing electron clouds away from equilibrium distribution. (for instance, benzene pi orbitals)
- Magnetic resonance—In a magnetic field, magnetic spin moments—nuclear spins—align with field.\ If we push a spin away from field, it will want to relax back.
- Scattering from Damped Harmonic Oscillator
- Assume that a molecule is a simple harmonic oscillator with a single harmonic oscillation frequency
- When irradiated by monochromatic electromagnetic wave of frequencyω0,theelectromagneticwaveoffrequencyω0,theelectron undergoes an acceleration, while the nucleus, being massive, is assumed not to move
- An accelerating charge gives rise to electromagnetic radiationelectromagneticradiation.
- Scattering is governed byftiid drefractive index andparticle size distributionparticlesizedistributio
Mie theory is the basis for calculation of the scattering and absorption coefficients of a spherical particle having a given diameter and refractive index
Mie theory, also called Lorenz-Mie theory or Lorenz-Mie-Debye theory, is an analytical yyysolution of Maxwell's equations for the scattering of electromagnetic radiation by spherical ti l( lll d Mitt i) i tfparticles (also calledMie scattering)in terms ofinfinite series. The Mie solution is named after its developer German physicist Gustav Miedeveloper, GermanphysicistGustavMie. However, others like Danish physicist Lorenz preceded him independently developed the ppyptheory of electromagnetic plane wave scattering by a dielectric sphere. The term "Mie solution" is sometimes used more generically for any analytical solution in terms of infinite series